Chemical Engineering Design and Analysis: An Introduction, second edition (2019)

Graphs for Chapter 4 Exercises

Solutions to chapter 4 exercises typically require exploring on maps and graphs. You may find it convenient to draft and submit solutions on maps and graphs downloaded from this site.

T. M. Duncan and J. A. Reimer

Printable Paper Rulers

Print these onto an overhead transparency for a ruler as good as you will need in this course.

Blank Graph Paper

Blank graph paper for all occasions, from The Sourcebook for Teaching Science

Textbook Section 4.1.3 (second edition)

Pressure-composition and temperature composition phase diagrams for benzene + toluene mixtures

Exercise 4.2

An energy-phase number line for Substance Q with a scale for temperature and phase.

Exercise 4.3

A blank number line for constructing a phenol energy-phase line.

Exercises 4.4 through 4.12

An energy-phase number line for H2O with a scale for temperature and phase.

Exercises 4.13 and 4.14

pressure-composition phase diagram for tetachloromethane+chlorobenzene mixtures.

Exercise 4.15

temperature-composition phase diagram for acetonitrile + 2-methylpyridine mixtures.

Exercises 4.16, 4.17, and 4.18

temperature-composition phase diagram for M + K mixtures.

Exercises 4.19 and 4.66

vapor-liquid equilibrium data for methanol + water mixtures at 1.0 atm.

Exercise 4.20

temperature-composition phase diagram for P+Q mixtures at 1 atm.

Exercise 4.21

pressure-composition and liquid-vapor phase diagrams for A+B mixtures at 1 atm.

Exercises 4.22 and 4.23

temperature-composition phase diagram for dimethylamine + 1-propanol mixtures at 1 atm.

Exercise 4.24

temperature-composition phase diagram for hexane+chlorobenzene mixtures at 1 atm.

Exercise 4.25

temperature-composition phase diagram for sugar+water mixtures at 1 atm.

Exercise 4.26

temperature-composition phase diagram for 1-butanol + water mixtures at 1 atm.

Exercise 4.27

ternary diagram for water+methanol+ethanol mixtures at 20C and 1 atm.

Exercise 4.28

ternary diagram for methylcyclopentane+hexane+aniline mixtures at 20C and 1 atm.

Exercise 4.29

ternary phase diagram for CO2 + A(aromatic) + P(polar) mixtures.

Exercise 4.30

ternary diagrams of liquid A and liquid B with different extracting liquids; X, Y or Z.

Exercises 4.31 and 4.97

ternary diagram for methylcyclohexane+heptane+aniline mixtures at 20C and 1 atm.

Exercise 4.32

temperature-composition phase diagrams for A+B mixtures and A+C mixtures.

Exercise 4.33

temperature-composition and enthalpy-composition phase diagrams for G+H mixtures.

Exercises 4.34 and 4.35

temperature-composition and enthalpy-composition phase diagrams for ammonia+water mixtures at 300 psia (20.4 atm).

Exercise 4.36

enthalpy-composition phase diagram for water+sulfuric acid mixtures at 1 atm.

Exercise 4.37

temperature-composition and enthalpy-composition phase diagrams for aceonitrile+nitromethane mixtures at 1 atm.

Exercises 4.39 and 4.40

O2/air - O2/blood solubility diagrams.

Exercise 4.41

ethanol/air - ethanol/blood solubility diagrams.

Exercise 4.42

X/water - X/cyclohexane solubility diagram.

Exercise 4.43

acetone/oil - acetone/air solubility diagram.

Exercises 4.44 and 4.45

Q/oil - Q/air solubility diagram.

Exercise 4.46

K/oil - K/air solubility diagram.

Exercise 4.47

acetone/air - acetone/oil solubility diagram.

Exercise 4.48

chloroform/oil - chloroform/air solubility diagram.

Exercise 4.50

Adsorption Isotherms for benzene over activated charcoal.

Exercise 4.52

water/sugar - water/salt solubility diagram.

Exercise 4.53

syrup - glue thermal diagram.

Exercises 4.54 and 4.66

blank graph for liquid-vapor x-y diagram for methanol + water mixtures.

Exercise 4.55

vapor-liquid equilibrium data for nitric acid + water mixtures at 1.0 atm.

Exercise 4.63

x-y diagram for liquid-vapor systems of acetonitrile + water mixtures at 1 atm.

Exercises 4.64 and 4.71

x-y diagram for liquid-vapor systems of acetonitrile + 2-methylpyridine mixtures at 1 atm.

Exercises 4.65 and 4.105

x-y diagram for liquid-vapor systems of ethanol + water mixtures at 1 atm.

Exercise 4.67

x-y diagram for liquid-vapor systems of F+Z mixtures at 1 atm.

Exercise 4.68

temperature-composition phase diagram and x-y vapor-liquid diagram for methanol+H2O mixtures.

Exercise 4.69

temperature-composition phase diagram and x-y vapor-liquid diagram for methanol+H2O mixtures.

Exercise 4.72

temperature-composition phase diagram and x-y vapor-liquid diagram for E+M mixtures.

Exercise 4.73

Pressure-Temperature Phase Diagram for Compound X

Exercises 4.74, 4.75, 4.76, 4.79, and 4.81

P-T phase diagram for H2O (0.001 to 1 atm).

Exercises 4.77 and 4.78

P-T phase diagram for H2O (0.001 to 10 atm).

Exercise 4.80

P-T phase diagram for CO2.

Exercise 4.82

P-T phase diagram for propane.

Exercise 4.83

P-T and P-V phase diagrams for H2O (0.00001 to 1000 atm).

Exercise 4.84

P-V phase diagram for Compound Z.

Exercises 4.85 and 4.86

P-V and P-T phase diagrams for 1,2-dichloroethane (1,2-DCA).

Exercise 4.87

P-T, P-V, and T-V phase diagrams for H2O (0.001 to 1000 atm).

Exercise 4.88

pressure-enthalpy diagram for ethylene.

Exercise 4.89

temperature-composition phase diagram for M + K mixtures.

Exercise 4.90

temperature-composition phase diagram for 1-butanol + water mixtures at 1 atm.

Exercise 4.91

phase diagram for P+Q mixtures at 1 atm.

Exercises 4.92 and 4.93

phase diagram for sodium + potassium mixtures.

Exercise 4.94

phase diagram for sodium sulfate solutions.

Exercise 4.95

phase diagram for magnesium sulfate solutions.

Exercise 4.96

ternary diagram for methylcyclopentane + hexane + aniline mixtures.

Exercises 4.31 and 4.97

ternary diagram for methylcyclohexane+heptane+aniline mixtures.

Exercise 4.98

ternary phase diagram for CO2+A(aromatic)+P(polar) mixtures. Temperature-composition diagrams for CO2+A and CO2+P mixtures

Exercise 4.99

ternary diagram for CH4+CO2+N2 mixtures at 40 atm and 220 K.

Exercise 4.100

ternary phase diagram for solids+oil+ethanol mixtures. Temperature-composition diagram for ethanol+oil mixtures

Exercise 4.101

ternary phase diagram for solids+P(liquid)+water mixtures. Temperature-composition diagram for water+P mixtures

Exercise 4.102

diagrams for separating A and B using solubility in water.

Exercise 4.103

ternary diagram for sugar+I+water mixtures.

Exercises 4.65 and 4.105

x-y diagram for liquid-vapor systems of ethanol + water mixtures at 1 atm.

Exercise 4.106

x-y diagram for 1,2-dichloroethane + 1-propanol mixtures at 1 atm.

Exercise 4.107

x-y diagrams for acetonitrile + water mixtures at 0.2 atm and 1 atm.

Exercise 4.108

W + R mixtures: temperature-composition phase diagram and x-y liquid-vapor diagram.

Exercise 4.109

temperature-composition and x-y diagrams for W+S mixtures.

Exercise 4.de.110

diagrams for separating A and B using extracting agent Z.

Exercise 4.111

Pressure-Temperature Phase Diagram for Chemical A

Exercise 4.113

diagrams for separating A and P, to get past an azeotrope.

Graphical Data for Olin Hall Distillation Column

temperature-composition and x-y maps of data for methanol-water mixtures.